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Deleting them manually will resolve the issue in this case.
Corrupted cache folder (MAC only) – There are several reports on Macs where the issue ends up being caused by a series of cache folders. In this case, forcing the browser to create a new profile will resolve the issue promptly.
Corrupted Chrome profile – File corruption inside your Chrome profile folder can also trigger this issue. In this case, you can resolve the issue by enabling the box associated with Offer to save passwords. Save password is disabled in Chrome – Chrome will not save any passwords (the prompt won’t appear) if you’ve previously configured if one option in the Autofill tab is disabled. If this scenario is applicable, you can disable this setting from Content Settings. Chrome is prohibited from saving local data – There’s one setting that, in case it’s enabled, might prevent your browser from remembering any of the passwords you end up saving. If you have an outdated client, simply updating the browser might resolve the issue automatically. Google Chrome bug – This particular issue is also known to be caused by a bug that has been since patched by Google.